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how to use the model tip per kontrate qeraje.17 hack app (ios).[study on chemical constituents of root of zanthoxylum piperitum]. to study the chemical constituents of the root of zanthoxylum piperitum. compounds were isolated and purified by chromatography on silica gel, sephadex lh-20 column chromatography, and preparative hplc, and their structures were identified by the spectroscopic methods. five compounds were isolated and identified as lignans, 2-(3,4-dimethoxyphenyl)-1-methoxyl-6-methoxy-7-methyl-(8beta,9beta,10beta)-abeo-agarofuran-7-ol (1), 1,2-bis-(3,4-dimethoxyphenyl)-3,4,5-trimethoxy-1-butene (2), beta-sitosterol (3), 2-methoxy-4-hydroxybenzaldehyde (4), and sinapaldehyde (5). compounds 1, 2, 4 and 5 are isolated from the genus zanthoxylum for the first time.hey there, time traveller! this article was published 21/9/2011 (3263 days ago), so information in it may no longer be current. in the span of 10 days, the city went from being all but sold out of free beer to a situation where it might as well have been sold out, as a result of a second-round of drinking restrictions imposed by the province. yes, if you bought a six-pack of molson canadian from the city's liquor stores yesterday, the next time you go to pick it up at the same outlets, you'll have to be prepared to pay a $5.50 government levy on top of that -- a fee that's been criticized by some beer retailers as a "tax grab." the province imposed a second round of drinking restrictions on wednesday, as a reaction to the province's own failed carbon monoxide testing campaign. in the first round of restrictions, the province ordered bars and restaurants to close their doors at 3 p.m. on weekdays. but many bars, restaurants and many independent liquor stores across the city simply weren't ready for that order. the damage was done: by the end of the day wednesday, the city was sold out of free molson, and some liquor stores were selling the brand for $7.50 a six-pack. retailers who were served with the order said they were caught completely off-guard by the sudden shutdown and added it left the city's liquor stores in a precarious position. "it's a bit of a mess," said michael blevins, the owner of annex liquor mart. "it's a free market; they are the ones making the decisions. if they are going to run it, they are the ones who are going to be responsible for it." blevins said the city's liquor stores were well within their rights to sell the beer for $7. but he said he was concerned the government was going to sell the same beer for $5. "now you are going to sell it for less than they are selling it for, so it's going to have an effect on their bottom line. the province could have at least waited a couple of weeks to do this." liquor store owners said the province should have consulted with them before imposing the new order.


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